As a freshman at Connecticut, Gordon ranked second on the team in scoring (12.6 ppg), despite coming off the bench for most of the season. He hit the game winning 3-point field goal against Villanova in the Big East Tournament. As a sophomore Gordon averaged a team-leading 19.5 points (which ranked 50th in the nation) and also led the Huskies with 156 total assists, which earned Gordon Second Team All-Big East honors.
In Gordon's junior and final year at Connecticut, he averaged a team-leading 20.5 points (again ranked 50th in the nation), 4.7 rebounds and 4.5 assists. He also connected on 104 three-pointers, the second-highest single season total in Connecticut's history. Gordon set a Big East Tournament record with 81 total points, earning the tournaments' Most Outstanding Performer honors. Gordon also earned Most Outstanding Player of the Phoenix Regional honors in the NCAA Tournament. He also led the tournament field with 127 total points, as he helped lead the Huskies to the NCAA Championship